Misaki Ayuzawa is the first female student council president at a once all-boys school turned co-ed. She rules the school with strict discipline demeanor. But she has a secret, she works at a maid cafe due to her families circumstances. One day the popular A-student and notorious heart breaker Takumi Usui finds out her secret and makes a deal with her to keep it hush from the school in exchange for spending some time with him.
| Title | Time | |
|---|---|---|
| 1 | Misaki Is a Maid! | 2010-04-02 |
| 2 | A Maid Even at the Campus Festival! | 2010-04-08 |
| 3 | What Color is Misaki? Natural Color? | 2010-04-15 |
| 4 | Net Idol Aoi | 2010-04-22 |
| 5 | First Time Minding the Shop | 2010-04-29 |
| 6 | Men & the Ayuzawa Cram School | 2010-05-06 |
| 7 | Enter the Student Council President of Miyabigaoka | 2010-05-13 |
| 8 | Misaki Goes to Miyabigaoka | 2010-05-20 |
| 9 | Maid-Sama Does Momotaro | 2010-05-27 |
| 10 | Sakura's Indie-Label Love | 2010-06-03 |
| 11 | The Secret of Takumi Usui Approaches! | 2010-06-10 |
| 12 | Maid Sama & the Sports Festival | 2010-06-17 |
| 13 | Idiots & Juveniles & Heroes &... | 2010-06-24 |
| 14 | Soutane Kano of Class 1-7 | 2010-07-01 |
| 15 | Bespectacled Rabbit at the Open Campus | 2010-07-08 |
| 16 | Maid Latte at the Beach House | 2010-07-15 |
| 17 | Usui Becomes the Enemy | 2010-07-22 |
| 18 | Maid Sama is a Footman | 2010-07-29 |
| 19 | Footman Through a Change of Pairs | 2010-08-05 |
| 20 | The Vice President is a Prince?! / Aoi and Her Fun Companion | 2010-08-12 |
| 21 | Usui's Rival?! Hinata Shintani | 2010-08-19 |
| 22 | Tag at the Forest School | 2010-08-26 |
| 23 | Maid Latte & a Whole Bunch of Sweets | 2010-09-02 |
| 24 | Lovey-Dovey Through Latte Magic ♥ | 2010-09-09 |
| 25 | Hinata & Misaki & Usui | 2010-09-16 |
| 26 | Too Cruel Ayuzawa & Usui the Idiot! | 2010-09-23 |
