Haruto Tokishima, a high school student, discovers Valvrave, a mysterious and very powerful machine, and after controlling it Haruto becomes immortal.
| Title | Time | |
|---|---|---|
| 1 | Revolutionary Transfer Student | 2013-04-12 |
| 2 | Beyond 666 | 2013-04-19 |
| 3 | L-Elf's Prophecy | 2013-04-26 |
| 4 | The Valvrave is the Hostage | 2013-05-03 |
| 5 | The Sakimori Academy Sings | 2013-05-10 |
| 6 | Saki's Comeback | 2013-05-17 |
| 7 | Haruto Under the Ruins | 2013-05-24 |
| 8 | Princess of Light | 2013-05-31 |
| 9 | Dog and Thunder | 2013-06-07 |
| 10 | Campaign Promise of Love | 2013-06-14 |
| 11 | Military Tribunal #54 | 2013-06-21 |
| 12 | The Heretic Activates | 2013-06-28 |
| 13 | A Cursed Bond | 2013-10-11 |
| 14 | Siblings of the Atmosphere | 2013-10-18 |
| 15 | Return to Karlstein | 2013-10-25 |
| 16 | Marie Set Free | 2013-11-01 |
| 17 | The Rune Abyss | 2013-11-08 |
| 18 | A Father's Wish | 2013-11-15 |
| 19 | Sadness is Like the Falling Snow | 2013-11-22 |
| 20 | The Kamitsuki Exposed | 2013-11-29 |
| 21 | The Cost of Lies | 2013-12-06 |
| 22 | Fist of the Moon | 2013-12-13 |
| 23 | The Operation to Retake Module 77 | 2013-12-20 |
| 24 | Revolution to the Future | 2013-12-27 |