Rentaro Aijo was rejected 100 times in middle school. He visits a shrine and prays for better luck in high school. The God of Love appears and promises that he'll soon meet 100 people he's destined to date. But there's a catch—once destiny introduces someone to him, the two must happily love each other. If they don't, they'll die. What will befall Rentaro and his 100 girlfriends in high school?
| Title | Time | |
|---|---|---|
| 1 | The 2 Girlfriends Who Really, Really, Really Love You (98 To | 2023-10-08 |
| 2 | First Kiss | 2023-10-15 |
| 3 | The Quiet Princess, the Knight, and the Samurai | 2023-10-22 |
| 4 | Just When You Think It's a Hanky-Panky Episode | 2023-10-29 |
| 5 | The Hyper-Efficient Girl | 2023-11-05 |
| 6 | Everyone's Favorite: The Swimsuit Episode | 2023-11-12 |
| 7 | Saying Hello to the Chemistry Girl | 2023-11-19 |
| 8 | Kiss Zombie Panic | 2023-11-26 |
| 9 | The Holy War of Love and Soul | 2023-12-03 |
| 10 | Love Mission: Impossible | 2023-12-10 |
| 11 | Even If It Kills Me | 2023-12-17 |
| 12 | The 100 Girlfriends Who Really, Really, Really, Really, REAL | 2023-12-24 |
| 13 | Her Name. | 2025-01-12 |
| 14 | The Beginning and the End! Food Fight Festival! | 2025-01-19 |
| 15 | What Does the Maid See? | 2025-01-26 |
| 16 | Super Soaked Maid Party | 2025-02-02 |
| 17 | Most Athletes Are Masochists | 2025-02-09 |
| 18 | A Homerun Promise | 2025-02-16 |
| 19 | Karaoke Crisis | 2025-02-23 |
| 20 | The Beautiful and the Bold | 2025-03-02 |
| 21 | The World Hair Only Grows | 2025-03-09 |
| 22 | Peekaboy-Meets-Girl | 2025-03-16 |
| 23 | Tsundere Lost | 2025-03-23 |
| 24 | The 100 Girlfriends Who Really, Really, Really, Really, REAL | 2025-03-30 |
| 25 | Episode 25 | 2026-07-05 |
