Agents Napoleon Solo and Illya Kuryakin work for a secret intelligence service working under the auspices of the U.N. Their immediate superior is Mr. Waverly. Together they operate out of a secret base beneath the streets of New York City, and accesses through several cover business such as Del Floria's Tailor Shop and the Masque Club. This secret intelligence service is called U.N.C.L.E. United Network Command for Law and Enforcement.
| Title | Time | |
|---|---|---|
| 1 | The Vulcan Affair | 1964-09-22 |
| 2 | The Iowa Scuba Affair | 1964-09-29 |
| 3 | The Quadripartite Affair | 1964-10-06 |
| 4 | The Shark Affair | 1964-10-13 |
| 5 | The Deadly Games Affair | 1964-10-20 |
| 6 | The Green Opal Affair | 1964-10-27 |
| 7 | The Giuoco Piano Affair | 1964-11-10 |
| 8 | The Double Affair | 1964-11-17 |
| 9 | The Project Strigas Affair | 1964-11-24 |
| 10 | The Finny Foot Affair | 1964-11-24 |
| 11 | The Neptune Affair | 1964-12-08 |
| 12 | The Dove Affair | 1964-12-15 |
| 13 | The King of Knaves Affair | 1964-12-22 |
| 14 | The Terbuf Affair | 1964-12-29 |
| 15 | The Deadly Decoy Affair | 1965-01-11 |
| 16 | The Fiddlesticks Affair | 1965-01-18 |
| 17 | The Yellow Scarf Affair | 1965-01-25 |
| 18 | The Mad, Mad, Tea Party Affair | 1965-02-01 |
| 19 | The Secret Sceptre Affair | 1965-02-08 |
| 20 | The Bow-Wow Affair | 1965-02-15 |
| 21 | The Four-Steps Affair | 1965-02-22 |
| 22 | The See-Paris-and-Die Affair | 1965-03-01 |
| 23 | The Brain-Killer Affair | 1965-03-08 |
| 24 | The Hong Kong Shilling Affair | 1965-03-15 |
| 25 | The Never-Never Affair | 1965-03-22 |
| 26 | The Love Affair | 1965-03-28 |
| 27 | The Gazebo in the Maze Affair | 1965-04-05 |
| 28 | The Girls of Nazarone Affair | 1965-04-12 |
| 29 | The Odd Man Affair | 1965-04-19 |
